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After the SR template is de ned and designed, integrating the CAD with PACS can be implemented by using the toolkit. The rst step is to use a PACS simulator to verify the data ow, as shown in Figure 26.11. The PACS simulator has been used since 2000 in the IPILab, USC as a training tool for PACS and imaging informatics research and development, and to verify the HIPAA compliance; the PACS simulator is currently utilized as a research tool in CAD PACS integration. The integrating steps can be summarized as follows (see numerals in Fig. 26.11): (1) the i-CAD module is con gured with the MS SR template and all data (measurements, nodule images, and summary) to create the DICOM SR object; (2) the CAD WS is con gured to run the CAD application automatically after receiving DICOM images from modality simulator or PACS simulator; (3) based on the SR template,

Because ESPD is trying to discard packets from a few sessions only, it is possible that the buffer occupancy will not go below LB for an excessively long period, so that the targeted sessions in the drop list may lose fair access to network resources For this reason, the target sessions are removed from the drop list if the drop timer expires In w14x, it has been shown that ESPD can enhance fairness and significantly improve throughput over EPD with only a modest increase of implementation complexity 614 Dynamic Threshold with Single Loss Priority The dynamic threshold with single loss priority in a shared memory w15x works as follows Define the port-i occupancy Q i t as the length of the queue at port i at time t, and define the total occupancy Q t as the sum of all the port queue lengths in the shared memory.

alkoxide, or acyl, then case 2 (nucleophilic acyl substitution) is the probable course Hydrolyses of esters, amides, acid halides, and acid anhydrides t this case, as do partial reductions of acids or esters to aldehydes or ketones or the addition of organometallics to esters If R1 and R2 are H, alkyl, or aryl and Nu is a H, alkyl, or aryl anion (a metal hydride or organometallic), then the intermediate alkoxide will be the stable product and this is usually protonated to form the alcohol (case 3) Approach of the nucleophile to the carbon via a path perpendicular to the planar face of the carbonyl is relatively unhindered.

10. Start the LINE command. At the Specify first point: prompt, press Enter to continue the line in the same direction as the end of the arc. At the Length of line: prompt, type 1-13/16 . End the LINE command. 11. Choose Arc from the Draw toolbar. Follow the prompts:

However, steric hindrance may be su ciently severe to prevent reaction if the carbonyl is embedded in a crowded region of the molecule or if R1 and/or R2 are su ciently bulky that increased crowding in the transition structure (which will resemble the tetrahedral intermediate) raises the activation barrier to too high a value The carbonyl group is particularly sensitive to attack by nucleophiles which themselves contain an X: substituent The rate enhancement due to the presence of the X: substituent is greater than observed in the case of nucleophilic attack at saturated carbon (SN 2, see 9) Several theories have been proposed for the ``extra'' reactivity [190 192] The simplest proposes a four-center interaction between the LUMO (pCO ) and the HOMO of the nucleophile nNuc X which is in fact an occupied p orbital and has the correct nodal characteristics for e ective overlap.

9. Use the HIDE command again to see the result. 10. Save your drawing. It should look like Figure 24-19. If you re continuing on to the next exercise, leave it open.

The four-electron repulsive component of the interaction is easily relieved if the geometry of the transition state is as shown in Figure 84 Cyclohexanones in which the chair inversion is constrained by substitution undergo diastereoselective nucleophilic addition, the nature of which (ie, preferentially axial or preferentially equatorial) depends on the nature of the substituents The explanation of this e ect has been extensively explored [95, 189, 193 197] The simplest explanation, shown in Figure 85, involves a distortion of the carbonyl group from planarity in such a way as to improve p-type donation from the ring C C s bond or the axial s bond (often a C H bond) in the position, whichever is the better donor A secondary e ect is the improved interaction between the distorted p orbital and the HOMO of the.

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